Uber die Darstellung, spektroskopische Charakterisierung und Kristallstruktur von Trifluormethylazosulfbn-N,N-dimethylamid (CH3)2N S(0)2NNCF3 On the Preparation, Spectroscopic Characterization and Crystal Structure of Trifluoromethylazosulfon-N,N-dimethylamid (CH3)2N S (0 )2NNCF3
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چکیده
Trifluormethylazosulfon-N,N-dimethylamid, Vibrational Spectra, NMR Spectra, Mass Spectra, Crystal Structure The reaction of Trifluoronitrosomethan with (CH3)2NS(0 )2NH2 in THF and Na2C 0 3 as base give the yellow liquid (CH3)2NS(0 )2NNCF3. The new compound melts at 283 K and were characterized by vibrational, NMR and mass spectra. In addition, the crystal structure of (CH3)2NS(0 )2NNCF3 has been determinated.The azocompound crystallizes in the orthorhombic space group Pnma with a = 1196.7(8), b = 876.9(6), c = 781.5(6) pm, ß = 90° and four formula units per unit cell.
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